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- Title
Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu).
- Authors
Cruz-Navarro, Jesús Antonio; Sánchez-Mora, Arturo; Serrano-García, Juan S.; Amaya-Flórez, Andrés; Colorado-Peralta, Raúl; Reyes-Márquez, Viviana; Morales-Morales, David
- Abstract
The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant growth due to the price increase of noble metals and their scarce abundance. As a result, many earth-abundant transition-metal complexes containing nickel, iron, or cobalt have been successfully applied in the homogeneous catalysis of a wide number of cross-coupling reactions, and the use of pincer complexes based on these earth-abundant metals was recently explored, affording interesting results. Thus, this review provides a general overview of earth-abundant 3D pincer complexes and their application during the last decade as catalysts in cross-coupling reactions such as Kumada–Corriu, Suzuki–Miyaura, Sonogashira, C–S cross-coupling, and C–N bond-forming reactions.
- Subjects
COPPER; PRECIOUS metals; METALS; HOMOGENEOUS catalysis; ORGANIC chemistry; COBALT; IRON; SUZUKI reaction
- Publication
Catalysts (2073-4344), 2024, Vol 14, Issue 1, p69
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal14010069