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- Title
Lanthanides Mediated Oxidative Cross Coupling of Benzylalcohol and Various Amines to Form Corresponding Imines.
- Authors
Bhattacharjee, Jayeeta; Sachdeva, Mitali; Panda, Tarun K.
- Abstract
Herein, a new and efficient approach towards the oxidative cross-coupling of benzylalcohol and various aromatic amines to form corresponding imines with high degree conversion (>80 %) and chemo-selectivity using lanthanide salts as pre-catalysts is presented. The catalyzed oxidative cross-coupling reaction using La(NO3)3 ·6H2O as pre-catalyst displayed a broad substrate scope. The reaction afforded various substituted imines from the reaction of benzylalcohol with ample variety of amines in good yields.
- Subjects
RARE earth metals; COUPLING reactions (Chemistry); BENZYL alcohol; IMINES; AMINES
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2016, Vol 642, Issue 17, p937
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201600201