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- Title
The Dual Reactivity of 5- S/5- O-Phenyl-1,4,2-oxathiazoles: A Fragmentation Pathway That Affords Nitriles in the Presence of Water.
- Authors
Lim, Yi Wee; Hewitt, Russell J.; Burkett, Brendan A.
- Abstract
The rearrangement of substituted 1,4,2-oxathiazoles to nitriles in the presence of water is described. Preliminary investigations suggest that the reaction pathway proceeds via a 1,4,2-oxathiazolium intermediate, followed by trapping with water and subsequent decomposition to products.
- Subjects
REARRANGEMENTS (Chemistry); THIAZOLIUM compounds; NITRILES; WATER; CHEMICAL decomposition
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 22, p4840
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201500637