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- Title
34 GHz Pulsed ENDOR Characterization of the Copper Coordination of an Amyloid β Peptide Relevant to Alzheimer's Disease.
- Authors
Kim, Donghun; Kim, Nam Hee; Kim, Sun Hee
- Abstract
The copper(II) ion coordination mode of CuII‐Aβ(1–16) at physiological pH was characterized by 34 GHz pulsed ENDOR spectroscopy. 1H/2H ENDOR and 14N ENDOR demonstrate the NH2 terminus of aspartic acid is an equatorial ligand of CuII, and 17O ENDOR together with 1H ENDOR suggest that water is an axial ligand (see picture; Cu pink, O red, N blue).
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 4, p1139
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201208108