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- Title
Using N-Tosylhydrazone as a Double Nucleophile in the Palladium-Catalyzed Cross-Coupling Reaction To Synthesize Allylic Sulfones.
- Authors
Zhou, Ping ‐ Xin; Ye, Yu ‐ Ying; Zhao, Lian ‐ Biao; Hou, Jian ‐ Ye; Kang, Xing; Chen, Dao ‐ Qian; Tang, Qian; Zhang, Jie ‐ Yu; Huang, Qi ‐ Xing; Zheng, Lan; Ma, Jun ‐ Wei; Xu, Peng ‐ Fei; Liang, Yong ‐ Min
- Abstract
Without extra addition of sulfinate salt, allylic sulfones were synthesized by palladium-catalyzed cross-coupling of aryl iodide with N-tosylhydrazone. In this transformation, not only the diazo compound but also the sulfinate salt, which were both generated in situ from base-mediated decomposition of the N-tosylhydrazone, was used as nucleophilic partner.
- Subjects
SULFINATES; SULFONES; PLATINUM group; CATALYSIS; ARYL iodides; NUCLEOPHILES
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 49, p16093
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201405172