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- Title
Supramolecular Crystal Networks Constructed from Cucurbit[8]uril with Two Naphthyl Groups.
- Authors
Gao, Zhong-Zheng; Shen, Lei; Hu, Yu-Lu; Sun, Ji-Fu; Wei, Gang; Zhao, Hui
- Abstract
Naphthyl groups are widely used as building blocks for the self-assembly of supramolecular crystal networks. Host–guest complexation of cucurbit[8]uril (Q[8]) with two guests NapA and Nap1 in both aqueous solution and solid state has been fully investigated. Experimental data indicated that double guests resided within the cavity of Q[8], generating highly stable homoternary complexes NapA2@Q[8] and Nap12@Q[8]. Meanwhile, the strong hydrogen-bonding and π···π interaction play critical roles in the formation of 1D supramolecular chain, as well as 2D and 3D networks in solid state.
- Subjects
CUCURBITACEAE; SOLID solutions; CRYSTALS; AQUEOUS solutions; HOST-guest chemistry
- Publication
Molecules, 2023, Vol 28, Issue 1, p63
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules28010063