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- Title
The Effect of Sulphate Anions on the Ultrafine Titania Nucleation.
- Authors
Kotsyubynsky, Volodymyr; Myronyuk, Ivan; Chelyadyn, Volodymyr; Hrubiak, Andriy; Moklyak, Volodymyr; Fedorchenko, Sofia
- Abstract
The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)(OH)] mononers is the determinative factor for anatase phase nucleation.
- Subjects
TITANIUM tetrachloride; SULFATES; TITANIUM dioxide; HYDROLYSIS; CHELATING agents
- Publication
Nanoscale Research Letters, 2017, Vol 12, Issue 1, p1
- ISSN
1931-7573
- Publication type
Article
- DOI
10.1186/s11671-017-2144-3