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- Title
New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide.
- Authors
Monreal, Marisa J.; Seaman, Lani A.; Goff, George S.; Michalczyk, Ryszard; Morris, David E.; Scott, Brian L.; Kiplinger, Jaqueline L.
- Abstract
Two organometallic 1D infinite coordination polymers and two organometallic monometallic complexes of thorium diazide have been synthesized and characterized. Steric control of these self-assembled arrays, which are dense in thorium and nitrogen, has also been demonstrated: infinite chains can be circumvented by using steric bulk either at the metallocene or with a donor ligand in the wedge.
- Subjects
ORGANOMETALLIC compounds; ORGANIC synthesis; COORDINATION polymers; METALLURGY of thorium; THORIUM compounds; STERIC factor (Chemistry); METALLOCENES; LIGAND binding (Biochemistry); WEDGES
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 11, p3631
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201510851