We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Hydrogen sulfide adducts of methyl oleate and linoleate.
- Authors
Schwab, A.; Rohwedder, W.; Tjarks, L.; Gast, L.
- Abstract
Sulfur compounds derived from photochemical addition of hydrogen sulfide to methyl oleate and linoleate were separated by preparative gas chromatography. The major compounds were investigated by NMR, mass and IR spectroscopy and by elemental analysis. The primary product of the methyl oleate reaction was methyl 9(10)-mercaptostearate. Gas chromatograms of the product from methyl linoleate showed four principal peaks. From mass spectra and NMR data, we identified methyl 9-(2-pentyl-1-thiolan-5-yl)nonanoate, methyl 8-(2-hexyl-1-thiolan-5-yl)octanoate and methyl 9-(3-hexyl-1,2-dithiolan-5-yl)nonanoate. Evidence for the formation of methyl mercapto-octadecenoates and methyl dimercaptostearates was also obtained.
- Publication
Journal of the American Oil Chemists' Society (JAOCS), 1973, Vol 50, Issue 9, p364
- ISSN
0003-021X
- Publication type
Article
- DOI
10.1007/BF02640841