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- Title
Degradable Superhydrophilic Iron‐Pillared Bentonite Doped with Polybutylene Adipate/Terephthalate Open‐Cell Foam: Its Application in Dye Degradation, Removal of Heavy Metal Ions, and Oil–Water Separation.
- Authors
Qiu, Liyan; Phule, Ajit Dattatray; Zhong, Weipeng; Wen, Shibao; Zhang, Zhenxiu
- Abstract
Development of industrialization has brought convenience to people's lives; however, it has also brought serious harm to the environment, where, water pollution is the most obvious. Here, a polybutylene adipate terephthalate (PBAT) open‐cell foam doped with iron‐pillared bentonite (IPB) is prepared by using sugar as a pore‐forming agent and solution phase separation, and then combined with a solution dipping method to coat the foam surface with a polyacrylamide/SiO2, which makes the PBAT foam superhydrophilic. The static adsorption effect of superhydrophilic IPB‐doped PBAT open‐cell foam on methylene blue (MB) and Cu2+ is studied. The adsorption isotherm fitting shows that the adsorption conforms to the Langmuir model and it has biased toward monolayer adsorption. The adsorption kinetics fitting confirms that the adsorption process is in line with the pseudo‐second‐order adsorption model, which is dominated by chemical adsorption. The modified PBAT open‐cell foam has an adsorption effect on Cu2+; however, it has weak cyclic adsorption capacity. It shows a good cyclic adsorption ability for the cationic dye MB and it has >95% photodegradation efficiency of the MB after five time's cyclic adsorption. The superhydrophilicity makes the foam to have better applications in oil–water separation.
- Subjects
FOAM; LANGMUIR isotherms; METAL ions; HEAVY metals; BENTONITE; ADSORPTION kinetics; POLYACRYLAMIDE; BASIC dyes
- Publication
Macromolecular Materials & Engineering, 2021, Vol 306, Issue 12, p1
- ISSN
1438-7492
- Publication type
Article
- DOI
10.1002/mame.202100481