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- Title
Conformationally induced electrostatic stabilization (CIES) of persulfoxides. A comparison to homologous sulfoxides.
- Authors
Clennan, Edward L.; Hightower, Sean E.
- Abstract
Computational and experimental evidence that participation of a remote heteroatom occurs during the formation and decomposition of persulfoxides is presented. The experimental ramifications of remote participation includes a dramatic increase in the rate of reaction with singlet oxygen and a decrease in the conformationally dependent ability of sulfides to physically deactivate singlet oxygen. The ability of different heteroatoms to participate is evaluated with a natural bond orbital analysis, and a comparison of the extent of participation in persulfoxides and their homologous sulfoxides is presented. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:591-599, 2007; Published online in Wiley InterScience (). DOI 10.1002/hc.20343
- Publication
Heteroatom Chemistry, 2007, Vol 18, Issue 5, p591
- ISSN
1042-7163
- Publication type
Article
- DOI
10.1002/hc.20343