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- Title
Bis(1‐Methyl‐ortho‐Carboranyl)Borane.
- Authors
Akram, Manjur O.; Tidwell, John R.; Dutton, Jason L.; Martin, Caleb D.
- Abstract
The Lewis superacid, bis(1‐methyl‐ortho‐carboranyl)borane, is rapidly accessed in two steps. It is a very effective hydroboration reagent capable of B−H addition to alkenes, alkynes, and cyclopropanes. To date, this is the first identified Lewis superacidic secondary borane and most reactive neutral hydroboration reagent.
- Subjects
BORANES; HYDROBORATION; ALKYNES; ALKENES; LEWIS acids
- Publication
Angewandte Chemie, 2023, Vol 135, Issue 34, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202307040