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- Title
Time-Resolved Interception of Multiple-Charge Accumulation in a Sensitizer-Acceptor Dyad.
- Authors
Mendes Marinho, Stéphanie; Ha‐Thi, Minh‐Huong; Pham, Van‐Thai; Quaranta, Annamaria; Pino, Thomas; Lefumeux, Christophe; Chamaillé, Thierry; Leibl, Winfried; Aukauloo, Ally
- Abstract
Biomimetic models that contain elements of photosynthesis are fundamental in the development of synthetic systems that can use sunlight to produce fuel. The critical task consists of running several rounds of light-induced charge separation, which is required to accumulate enough redox equivalents at the catalytic sites for the target chemistry to occur. Long-lived first charge-separated state and distinct electronic signatures for the sequential charge accumulated species are essential features to be able to track these events on a spectroscopic ground. Herein, we use a double-excitation nanosecond pump-pump-probe experiment to interrogate two successive rounds of photo-induced electron transfer on a molecular dyad containing a naphthalene diimide (NDI) linked to a [Ru(bpy)3]2+ (bpy=bipyridine) chromophore by using a reversible electron donor. We report an unprecedented long-lived two-electron charge accumulation ( t=200 μs).
- Subjects
CHEMICAL reactions; AMINES; MACROCYCLIC compounds; HETEROCYCLIC compounds; PHOTOEXCITATION
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 50, p16152
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201706564