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- Title
Trajectory of Approach of a Zinc-Hydrogen Bond to Transition Metals.
- Authors
Ekkert, Olga; White, Andrew J. P.; Crimmin, Mark R.
- Abstract
Through a dramatic advance in the coordination chemistry of the zinc-hydride bond, we describe the trajectory for the approach of this bond to transition metals. The dynamic reaction coordinate was interrogated through analysis of a series of solid state structures and is one in which the TM-H-Zn angle becomes increasingly acute as the TM-Zn distance decreases. Parallels may be drawn with the oxidative addition of boron-hydrogen and silicon-hydrogen bonds to transition metal centers.
- Subjects
ZINC hydrides; TRANSITION metals; TRAJECTORY measurements; DYNAMIC reaction path; OXIDATIVE addition
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 52, p16265
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201608599