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- Title
A Rigid Nested Metal-Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions.
- Authors
Gao, Qiang; Xu, Jian; Cao, Dapeng; Chang, Ze; Bu, Xian ‐ He
- Abstract
We herein report a rigid nested metal-organic framework (MOF) featuring a unique thermoresponsive gating adsorption behavior, which, in contrast to any known flexibility modes for stimuli-responsive MOFs, depends on the thermal motion of the extra-framework counterions. In addition, this MOF also exhibits adsorption selectivity of CO2 over N2, H2, and Ar at 273 K, thus enabling a strategic separation and encapsulation of CO2.
- Subjects
METAL-organic frameworks; THERMORESPONSIVE polymers; ENCAPSULATION (Catalysis); SINGLE crystals; THERMOGRAVIMETRY
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 48, p15251
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201608250