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- Title
Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation.
- Authors
Halder, Arjun; Kandambeth, Sharath; Biswal, Bishnu P.; Kaur, Gagandeep; Roy, Neha Chaki; Addicoat, Matthew; Salunke, Jagadish K.; Banerjee, Subhrashis; Vanka, Kumar; Heine, Thomas; Verma, Sandeep; Banerjee, Rahul
- Abstract
Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.
- Subjects
POROUS polymers; CHEMICAL synthesis; MOLECULAR structure; BLOCKS (Building materials); ROOFTOP construction
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 27, p7937
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201600087