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- Title
Sequential Interaction of Enamine with O, O-Dialkyldithiophosphoric Acid and Electrophilic Reagent.
- Authors
Khairullin, R. A.; Gazizov, M. B.; Kirillina, Yu. S.; Ivanova, S. Yu.; Shamsutdinova, L. P.
- Abstract
The adduct of O, O-dialkyldithiophosphoric acid and enamine reacts exothermically with an electrophilic reagent. In the case of sulfenyl bromide, the iminium salt reduced at the C-Br bond and bis(dialkoxythiophosphorylthio)-disulfide have been formed, experimentally evidencing the reaction of 2-halogenated ald- and ketimines with dithioic acid via the intermediate formation of enamine.
- Subjects
ELECTROPHILES; ACIDS; IMINES
- Publication
Russian Journal of General Chemistry, 2020, Vol 90, Issue 1, p84
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363220010120