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- Title
Features of the reaction of 3(5)-methyl-5(3)-trifluoromethylpyrazole with chloroform. Synthesis and structure of fluorinated analogs of tris(pyrazol-1-yl)methane.
- Authors
Boltacheva, N.; Slepukhin, P.; Pervova, M.; Samorukova, M.; Lavrenova, L.; Filyakova, V.; Charushin, V.
- Abstract
Reaction of 3(5)-methyl-5(3)-trifluoromethylpyrazole ( I) with chloroform leads to a complex mixture of compounds. The main components are {bis[(5-methyl-3-trifluoromethyl)pyrazol-1-yl](3-methyl-5-trifluoromethyl)pyrazol-1-yl}methane, bis{[(3-methyl-5-trifluoromethyl)pyrazol-1-yl](5-methyl-3-trifluoromethyl)-pyrazol-1-yl}methane, and tris[(3-methyl-5-trifluoro-methyl)pyrazol-1-yl]methane. The structure of isomeric substances was proved by XRD method.
- Subjects
CHEMICAL reactions; CHLOROFORM; METHANE; ISOMERS; PYRAZOLES
- Publication
Russian Journal of General Chemistry, 2012, Vol 82, Issue 8, p1444
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363212080191