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- Title
New Trendy Magnetic C-Scorpionate Iron Catalyst and Its Performance towards Cyclohexane Oxidation.
- Authors
Ribeiro, Ana P. C.; Matias, Inês A. S.; Alegria, Elisabete C. B. A.; Ferraria, Ana M.; Botelho do Rego, Ana M.; Pombeiro, Armando J. L.; Martins, Luísa M. D. R. S.
- Abstract
For the first time, a magnetic C-scorpionate catalyst was prepared from the iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) and ferrite, using the sustainable mechanochemical synthetic procedure. Its catalytic activity for the cyclohexane oxidation with tert-butyl hydroperoxide (TBHP) was evaluated in different conditions, namely under microwave irradiation and under the effect of an external magnetic field. The use of such magnetic conditions significantly shifted the catalyst alcohol/ketone selectivity, thus revealing a promising, easy new protocol for tuning selectivity in important catalytic processes.
- Subjects
SCORPIONATES; IRON catalysts; OXIDATION of cyclohexane
- Publication
Catalysts (2073-4344), 2018, Vol 8, Issue 2, p69
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal8020069