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- Title
Inherent dynamical preferences in carbocation rearrangements leading to terpene natural products.
- Authors
Pemberton, Ryan P.; Young J. Hong; Tantillo, Dean J.
- Abstract
An introduction to the application of quantum chemical dynamics calculations to mechanistic problems in the field of terpene biosynthesis is provided. A bare bones introduction to the fundamentals of chemical dynamics is followed by a brief account of previous applications to terpene-forming carbocation reactions, a discussion of questions in this field that dynamics calculations may help answer, and a description of current problems to which dynamics calculations are being applied.
- Subjects
CARBOCATIONS; REARRANGEMENTS (Chemistry); TERPENES synthesis; NATURAL products; QUANTUM chemistry; COMPUTATIONAL chemistry; QUANTUM theory
- Publication
Pure & Applied Chemistry, 2013, Vol 85, Issue 10, p1949
- ISSN
0033-4545
- Publication type
Article
- DOI
10.1351/PAC-CON-12-11-22