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- Title
Photoswitching CO<sub>2</sub> Capture and Release in a Photochromic Diarylethene Metal-Organic Framework.
- Authors
Luo, Feng; Fan, Cong Bin; Luo, Ming Biao; Wu, Xiao Liu; Zhu, Yan; Pu, Shou Zhi; Xu, Wen‐Yuan; Guo, Guo‐Cong
- Abstract
We demonstrate herein a promising pathway towards low-energy CO2 capture and release triggered by UV and visible light. A photosensitive diarylethene ligand was used to construct a photochromic diarylethene metal-organic framework (DMOF). A local photochromic reaction originating from the framework movement induced by the photoswitchable diarylethene unit resulted in record CO2-desorption capacity of 75 % under static irradiation and 76 % under dynamic irradiation.
- Subjects
PHOTOCHROMIC materials; METAL-organic frameworks; ORGANOMETALLIC compounds; IRRADIATION; DESORPTION
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 35, p9298
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201311124