We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Synthesis of Rh<sup>III</sup> Anilido, Hydroxide, and Methoxide Complexes.
- Authors
Burgess, Samantha A.; Bolaño, Tamara; Gunnoe, T. Brent; Sabat, Michal; Myers, William H.
- Abstract
The octahedral RhIII complexes [( tbpy)2Rh(XH)2][OTf]3 ( tbpy = 4,4′-di- tert-butyl-2,2′-bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [( tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [( tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [( tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5-bis-trifluoromethyl)phenyl]borate), [( tbpy)2Rh(Me)(NHPh)][BAr′4], [( tbpy)2Rh(OMe)(Cl)]Cl, and [(bpy)Rh(X)2][PF6] (bpy = 2,2′-bipyridyl; X = OH, OMe) have been synthesized and characterized by 1H, 13C{1H}, and 19F NMR spectroscopy, elemental analysis, or high-resolution mass spectrometry as well as single-crystal X-ray diffraction for some complexes. A comparison of the solid-state structural data for [( tbpy)2Rh(Me)(NH2Ph)]2+, [( tbpy)2Rh(NH2Ph)2]3+, [( tbpy)2Rh(NHPh)2]+, and [( tbpy)2Rh(NHPh)(NH2Ph)]2+ is included.
- Subjects
RHODIUM compounds; ANIONS; NUCLEAR magnetic resonance spectroscopy; MASS spectrometry; LIGANDS (Chemistry); HYDROXIDES
- Publication
European Journal of Inorganic Chemistry, 2015, Vol 2015, Issue 6, p1041
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201403147