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- Title
'Hot'-Atom Chemistry of Radiocobalt in Hexamminecobalt(III) Hexacyanocobaltate(III) and Hexamminecobalt(III) Hexacyanoferrate(III).
- Authors
SAITO, NOBUFUSA; TOMINAGA, TAKESHI; SANO, HIROTOSHI
- Abstract
BEHAVIOUR of cobalt-60 recoils arising from thermal neutron capture and isomeric transition on cobalt atoms in either hexamminecobalt(III) complex salts or hexacyanocobaltate(III) complex salts has already been investigated1-6. However, the system which contains both NH3 and CN groups together has not yet been investigated. In order to elucidate the role of CN groups in recoil reactions, we selected, as such a system, two complex salts of the formula [Co(NH3)6] [M(CN)6], where M = Co or Fe, since no hexammine-cobalt(III) cyanide is known at present.
- Publication
Nature, 1962, Vol 194, Issue 4827, p466
- ISSN
0028-0836
- Publication type
Article
- DOI
10.1038/194466b0