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- Title
Nickel‐Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron‐Substituted Quaternary Carbons and Regiodivergent Reactions.
- Authors
Chen, Liang‐An; Lear, Alan R.; Gao, Pin; Brown, M. Kevin
- Abstract
A method for the construction of boron‐substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2‐disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed.
- Subjects
CARBON; PALLADIUM; CONSTRUCTION
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 32, p11072
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201904861