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- Title
Room‐Temperature Functionalization of N<sub>2</sub> to Borylamine at a Molybdenum Complex.
- Authors
Espada, Maria F.; Bennaamane, Soukaina; Liao, Qian; Saffon‐Merceron, Nathalie; Massou, Stéphane; Clot, Eric; Nebra, Noel; Fustier‐Boutignon, Marie; Mézailles, Nicolas
- Abstract
Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)MoIV–nitrido complex generated by N2 splitting is reported. The imido–hydride and di‐hydride–amido MoIV complexes have been isolated and characterized. Addition of PinBH to the [Mo(H)2(N(BPin)2)]+ complex at room temperature results in the liberation of borylamines from the metal center.
- Subjects
IONIC liquids; AMINE analysis; MOLYBDENUM; CHROMIUM group; CHEMICAL reactions
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 39, p13047
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201805915