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- Title
All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed CH Functionalization and 1,4-Migration.
- Authors
Burns, David J.; Best, Daniel; Wieczysty, Martin D.; Lam, Hon Wai
- Abstract
1,3-Enynes containing allylic hydrogens cis to the alkyne function as three-carbon components in rhodium(III)-catalyzed, all-carbon [3+3] oxidative annulations to produce spirodialins. The proposed mechanism of these reactions involves the alkenyl-to-allyl 1,4-rhodium(III) migration.
- Subjects
ALLYLATION; ANNULATION; HOMOGENEOUS catalysis; RHODIUM catalysts; ISOMERIZATION
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 34, p10096
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201503978