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- Title
Investigation of Water Splitting Reaction by a Multicopper Oxidase through X‐ray Absorption Nanospectroelectrochemistry (Adv. Energy Mater. 47/2022).
- Authors
Sedenho, Graziela C.; Neckel, Itamar T.; Colombo, Rafael N. P.; Pacheco, Jéssica C.; Bertaglia, Thiago; Crespilho, Frank N.
- Abstract
Bioelectrocatalysis, microspectroelectrochemistry, multicopper oxidases, water oxidation, X-ray absorption spectroscopy In article number 2202485, Frank N. Crespilho, and co-workers demonstrate the high-valent copper character of the enzyme active site during the water oxidation bioelectrocatalysis through X-ray absorption nanospectroelectrochemistry. Keywords: bioelectrocatalysis; microspectroelectrochemistry; multicopper oxidases; water oxidation; X-ray absorption spectroscopy EN bioelectrocatalysis microspectroelectrochemistry multicopper oxidases water oxidation X-ray absorption spectroscopy 1 1 1 12/20/22 20221215 NES 221215 B Water Splitting b The water oxidation reaction catalyzed by bilirubin oxidase demonstrates an inverse proton dependence relative to the native oxygen reduction reaction.
- Subjects
X-ray absorption; MULTICOPPER oxidase; BILIRUBIN oxidase; PHOTOCATHODES; COPPER enzymes; OXIDATION of water
- Publication
Advanced Energy Materials, 2022, Vol 12, Issue 47, p1
- ISSN
1614-6832
- Publication type
Article
- DOI
10.1002/aenm.202270201