We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
The effects of Ti-excess non-stoichiometry on the energy storage performances of BNT-based thin films.
- Authors
Xie, Yanjiang; Hao, Hua; Cao, Minghe; Yao, Zhonghua; Liu, Hanxing
- Abstract
In this study, we proposed a novel method of adding large amount of excessive Ti in Bi0.5Na0.5TiO3-based thin film to improve its energy storage density. Ti-excess 0.94Bi0.5Na0.5TixO3-0.06BaTixO3 (BNBTx, x = 1.00, 1.05, 1.10, 1.15) thin films were successfully prepared by sol–gel method. It was found that the phase structure of the thin films kept unchanged with the increase of Ti content, and substantial improvements in microstructure and breakdown strength could be obtained by the addition of an excess of Ti in BNBTx thin films, as well as reduced leakage. As a result, improved energy storage density of 34 J/cm3 and energy storage efficiency of 48% were achieved simultaneously in BNBT1.15 thin film at a medium electric field of 2400 kV/cm. Furthermore, Ti-excess thin films showed high-dielectric constant with good temperature stability from 25 to 200 °C. These results demonstrate that Ti-excess BNBTx thin film is a potential system for energy storage materials.
- Publication
Journal of Materials Science: Materials in Electronics, 2023, Vol 34, Issue 16, p1
- ISSN
0957-4522
- Publication type
Article
- DOI
10.1007/s10854-023-10635-z