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- Title
1-Bromo-2-(cyclopropylidenemethyl)benzene: A Useful Building Block in the Palladium-Catalyzed Reaction of 2-Alkynylbenzenamine.
- Authors
Li, Shaoyu; Luo, Yong; Wang, Xiaocong; Guo, Minjie; Wu, Jie
- Abstract
A novel palladium-catalyzed domino reaction of 1-bromo-2-(cyclopropylidenemethyl)benzene and 2-alkynylbenzenamine is reported, which generates 2-(naphthalen-2-yl)benzenamines and 5 H-indeno[1,2- c]quinolines via 6- endo and 5- exo cyclization, respectively. The regioselectivity for the final outcome can be affected by phosphine and N-heterocyclic carbene ligands.
- Publication
Chemistry - An Asian Journal, 2012, Vol 7, Issue 7, p1691
- ISSN
1861-4728
- Publication type
Article
- DOI
10.1002/asia.201200122