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- Title
Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates.
- Authors
Viciano, Mónica; Muñoz, Bianca K.; Godard, Cyril; Castillón, Sergio; Reyes, Manuel L.; García‐Ruiz, Mónica; Claver, Carmen
- Abstract
High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.
- Subjects
MOLECULAR weights; NAPHTHALENE; METHYL groups; HEXANE; LIGANDS (Chemistry)
- Publication
ChemCatChem, 2017, Vol 9, Issue 20, p3974
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201701250