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- Title
Scandium(III) Trifluoromethanesulfonate Catalyzed Selective Reactions of Donor-Acceptor Cyclopropanes with 1,1-Diphenylethanols: An Approach to Polysubstituted Olefins.
- Authors
Zhu, Xiaoyan; Hong, Gang; Hu, Chen; Wu, Shengying; Wang, Limin
- Abstract
An unexpected synthetic approach to polysubstituted olefins through the scandium(III) trifluoromethanesulfonate catalyzed ring-opening reaction of donor-acceptor cyclopropanes with 1,1-diphenylethanols was developed. The reactions, which are experimentally easy to handle, feature tolerance of various functional groups and mild reaction conditions. On the basis of experimental evidence, a plausible mechanism was also proposed.
- Subjects
SCANDIUM compounds; METHANESULFONATES; CATALYSIS; STEREOSELECTIVE reactions; CYCLOPROPANE; ETHANOL; ALKENES
- Publication
European Journal of Organic Chemistry, 2017, Vol 2017, Issue 11, p1547
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201700221