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- Title
Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization.
- Authors
Challinor, Amy J.; Calin, Marc; Nichol, Gary S.; Carter, Neil B.; Thomas, Stephen P.
- Abstract
A simple alkylamine [( iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0.25-2 mol% iron catalyst and 1-25 mol% amine. Significantly, these reactions proceed in equal yield under both air and inert reaction conditions.
- Subjects
ALKYLAMINES; IRON; ALKENES; HYDROSILYLATION; HYDROBORATION
- Publication
Advanced Synthesis & Catalysis, 2016, Vol 358, Issue 15, p2404
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201600570