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- Title
An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and Alkenes via CH Functionalization.
- Authors
Yang, Lei; Zhang, Guoying; Huang, Hanmin
- Abstract
A rhodium(III)-catalyzed direct selective C-2 alkenylation reaction of indoles with alkenes has been developed with molecular oxygen as the sole oxidant. The rhodium/oxygen catalytic system is applicable to a broad range of indoles and alkenes, which provides a novel access to various C-2 alkenylated indoles and pyrroles.
- Subjects
RHODIUM catalysts; OXYGEN; INDOLE compounds; OXIDATION; ALKENES; CARBON-hydrogen bonds
- Publication
Advanced Synthesis & Catalysis, 2014, Vol 356, Issue 7, p1509
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201301107