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- Title
Cover Feature: Impact of Pore Size and Defects on the Selective Adsorption of Acetylene in Alkyne‐Functionalized Nickel(II)‐Pyrazolate‐Based MOFs (Chem. Eur. J. 46/2021).
- Authors
Afshariazar, Farzaneh; Morsali, Ali; Sorbara, Simona; Padial, Natalia M.; Roldan‐Molina, Esther; Oltra, J. Enrique; Colombo, Valentina; Navarro, Jorge A. R.
- Abstract
Cover Feature: Impact of Pore Size and Defects on the Selective Adsorption of Acetylene in Alkyne-Functionalized Nickel(II)-Pyrazolate-Based MOFs (Chem. Eur. J. 46/2021) Keywords: breakthrough curves; carbon capture; gas separation; computational modelling; temperature swing adsorption EN breakthrough curves carbon capture gas separation computational modelling temperature swing adsorption 11747 11747 1 08/19/21 20210816 NES 210816 B As a consequence of specific interactions b between acetylene molecules and alkyne, aromatic and hydroxide residues of metal clusters, two isoreticular nickel(II) pyrazolate-based metal-organic frameworks bearing alkyne moieties on the ligand backbones are suitable for the selective separation of the challenging acetylene over CO SB 2 sb gas mixture. Breakthrough curves, carbon capture, gas separation, computational modelling, temperature swing adsorption.
- Subjects
ACETYLENE; ADSORPTION (Chemistry); NICKEL; SEPARATION of gases
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 46, p11747
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202102543