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- Title
Macrokinetics of Mechanosynthesis in Solid-Gas Systems. I. Mathematical Simulation.
- Authors
Smolyakov, V.; Lapshin, O.; Maksimov, Yu.
- Abstract
A mathematical model for mechanosynthesis in solid-gas systems is constructed which includes the equations of mechanical-reactor heat balance, grinding, the excess-energy dynamics in the condensed substances, which determines the effect of mechanical activation on the chemical-reaction rate, and the reaction kinetics. A brief analysis of the model is presented. A description is given of two simplified models of independent significance derived from the general model, which can be studied by analytical methods. Synthesis in a preactivated system is studied in detail. Relations determining the characteristics of the synthesis are obtained. The accuracy of the analytical estimates is verified by numerical simulation.
- Subjects
GAS-solid interfaces; MATHEMATICAL models; MECHANICAL chemistry; CHEMICAL reactions; ANALYTICAL mechanics; HEAT balance (Engineering)
- Publication
Combustion, Explosion, & Shock Waves, 2005, Vol 41, Issue 5, p554
- ISSN
0010-5082
- Publication type
Article
- DOI
10.1007/s10573-005-0069-0