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- Title
Silica nanoparticles as a high efficient catalyst for the one-pot synthesis of 3-oxo-3-phenylpropanamid derivatives from isocyanides, phenylacetaldehyde and secondary amines.
- Authors
Ramazani, Ali; Dastanra, Kourosh; Nasrabadi, Fatemeh Zeinali; Karimi, Zahra; Rouhani, Morteza; Hosseini, Mehdi
- Abstract
Reaction of an isocyanide with an iminium ion intermediate, formed by reaction between 2-oxo-2-phenylacetaldehyde and a secondary amine in the presence of silica nanoparticles, proceeds smoothly at room temperature to afford ketoamide derivatives in high yields.
- Subjects
SILICA nanoparticles; CATALYSTS; CHEMICAL synthesis; CHEMICAL derivatives; ISOCYANIDES; ACETALDEHYDE derivatives; SECONDARY amines
- Publication
Turkish Journal of Chemistry, 2012, Vol 36, Issue 3, p467
- ISSN
1300-0527
- Publication type
Article