We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Aerobic hydrocarbon oxidation catalyzed by the vanadomolybdophosphate polyoxometalate, H<sub>5</sub>PV<sub>2</sub>Mo<sub>10</sub>O<sub>40</sub>, supported on mesoporous MCM 41.
- Authors
Khenkin, Alexander; Neumann, Ronny; Sorokin, Alexander; Tuel, Alain
- Abstract
The impregnation of H5PV2Mo10O40 polyoxometalate onto MCM 41 and amino modified MCM 41 materials provided mesoporous active catalysts with large surface areas for aerobic hydrocarbon oxidation using isobutyraldehyde as a reducing agent. The results of the oxidation of alkenes and alkanes gave product selectivities similar to those observed in the corresponding homogeneous reaction although catalytic activity was somewhat reduced. Under appropriate experimental conditions there was no leaching and the solid catalyst could be recovered and reused without loss in activity.
- Publication
Catalysis Letters, 1999, Vol 63, Issue 3/4, p189
- ISSN
1011-372X
- Publication type
Article
- DOI
10.1023/A:1019093727135