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- Title
Selective Debenzylation of Benzyl Protected Groups with Silia Cat Pd(0) under Mild Conditions.
- Authors
Pandarus, Valerica; Béland, François; Ciriminna, Rosaria; Pagliaro, Mario
- Abstract
The article examines a series of sol-gel entrapped Pd(0) heterogeneous catalysts for the O- and N-debenzylation of benzyl protected groups under considerably mild conditions. The versatility of the catalysts, trademarked as SiliaCat Pd(0), was first tested under a hydrogen balloon at room temperature with three different substrates. The catalyst was found to be an efficient for the selective debenzylation of different aryl benzyl ethers, benzyl amino-acids, and benzyl-protected sugars.
- Subjects
CATALYSTS; BENZYL compounds; BALLOONS; ETHERS; AMINO acids; ORGANIC compounds
- Publication
ChemCatChem, 2011, Vol 3, Issue 7, p1146
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201000420