We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Frontispiece: Ligand-Supported E<sub>3</sub> Clusters (E=Si-Sn).
- Authors
Pan, Sudip; Saha, Ranajit; Osorio, Edison; Chattaraj, Pratim K.; Frenking, Gernot; Merino, Gabriel
- Abstract
E3 (E = Si, Ge, Sn) clusters can be stabilized via the coordination with different Lewis bases (L) like cyclic (alkyl)(amino) carbene (cAAC), N‐heterocyclic carbene (NHC), saturated NHC, mesoionic carbenes, trimethylamine, pyridine, phosphinine and trimethylphosphine. The Frontispiece depicts the main source of stabilization,namely, L→E σ‐donation and L←E π‐back‐donation in cAAC stabilized E3 complexes, the former being dominant. For more details, see the Full Paper by S. Pan, G. Frenking, G. Merino et al. on page 7463 ff.
- Subjects
CARBENES; LIGANDS (Chemistry); AB initio quantum chemistry methods; GROUP 14 elements; CHEMICAL bonds
- Publication
Chemistry - A European Journal, 2017, Vol 23, Issue 31, pn/a
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201783163