We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Studies on organosilicon reactive intermediates VIII synthesis and photochemistry of di(α-thienyl) hexamethyltrisilane.
- Authors
Wu, Shihui; Luo, Yumei; Liu, Fei; Chen, Shiming
- Abstract
The synthesis of di(α-thienyl)hexamethyltrisilane (1) is described. In the photolysis of 1 with cyclohexene and methanol, an apparent radical reaction occurred. We suspect that the sulfur atom of the thienyl group strongly stabilizes an initially formed silyl radical. This idea was supported both by identifying typical radical reaction products and examining the ESR spectrum of an adduct obtained by use of a radical trap. © 1996 John Wiley & Sons, Inc.
- Publication
Heteroatom Chemistry, 1996, Vol 7, Issue 1, p45
- ISSN
1042-7163
- Publication type
Article
- DOI
10.1002/(SICI)1098-1071(199601)7:1<45::AID-HC8>3.0.CO;2-1