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- Title
Effect of H[sub 2]O on the partial photo-oxidation of ethylene over Cu/SiO[sub 2] photocatalyst.
- Authors
Ichihashi, Yuichi; Matsumura, Yasuyuki
- Abstract
Ethylene can be catalytically photo-oxidised with water as an oxidant over silica-supposed copper oxide evacuated at 973 K. Presence of Cu+ cations in the catalyst is evidened by X-ray Absorption Near-Edge Structure (XANES). Ethylene oxide is formed at 278 K with a selectivity higher than 80% by the irradiation with UV-filtered light longer than 280 nm.
- Subjects
ETHYLENE oxide; PHOTOOXIDATIVE stress; COPPER oxide; ETHYLENE; ULTRAVIOLET radiation; X-ray absorption near edge structure
- Publication
Research on Chemical Intermediates, 2003, Vol 29, Issue 7-9, p891
- ISSN
0922-6168
- Publication type
Article
- DOI
10.1163/156856703322601889