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- Title
Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis.
- Authors
Jamil, Md. A. R.; Siddiki, S. M. A. Hakim; Touchy, Abeda Sultana; Rashed, Md. Nurnobi; Poly, Sharmin Sultana; Jing, Yuan; Ting, Kah Wei; Toyao, Takashi; Maeno, Zen; Shimizu, Ken‐ichi
- Abstract
The use of triglycerides as an important class of biomass is an effective strategy to realize a more sustainable society. Herein, three heterogeneous catalytic methods are reported for the selective one‐pot transformation of triglycerides into value‐added chemicals: i) the reductive amination of triglycerides into fatty amines with aqueous NH3 under H2 promoted by ZrO2‐supported Pt clusters; ii) the amidation of triglycerides under gaseous NH3 catalyzed by high‐silica H‐beta (Hβ) zeolite at 180 °C; iii) the Hβ‐promoted synthesis of nitriles from triglycerides and gaseous NH3 at 220 °C. These methods are widely applicable to the transformation of various triglycerides (C4–C18 skeletons) into the corresponding amines, amides, and nitriles.
- Subjects
HETEROGENEOUS catalysis; AMIDES; TRIGLYCERIDES; NITRILES; AMINES; AMIDATION
- Publication
ChemSusChem, 2019, Vol 12, Issue 13, p3115
- ISSN
1864-5631
- Publication type
Article
- DOI
10.1002/cssc.201900365