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- Title
Highly Efficient and Reversible Covalent Patterning of Graphene: 2D‐Management of Chemical Information.
- Authors
Wei, Tao; Kohring, Malte; Chen, Muqing; Yang, Shangfeng; Weber, Heiko B.; Hauke, Frank; Hirsch, Andreas
- Abstract
Patterned graphene‐functionalization with a tunable degree of functionalization can tailor the properties of graphene. Here, we present a new reductive functionalization approach combined with lithography rendering patterned graphene‐functionalization easily accessible. Two types of covalent patterning of graphene were prepared and their structures were unambiguously characterized by statistical Raman spectroscopy together with scanning electron microscopy/energy‐dispersive X‐ray spectroscopy (SEM‐EDS). The reversible defunctionalization processes, as revealed by temperature‐dependent Raman spectroscopy, enable the possibility to accurately modulate the degree of functionalization by annealing. This allows for the management of chemical information through complete write/store/erase cycles. Based on our strategy, controllable and efficient patterning graphene‐functionalization is no longer a challenge and facilitates the development of graphene‐based devices.
- Subjects
GRAPHENE; RAMAN spectroscopy; X-ray spectroscopy; LITHOGRAPHY; RAMAN microscopy
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 14, p5651
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201914088