We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes.
- Authors
Su, Wei; Gong, Tian ‐ Jun; Lu, Xi; Xu, Meng ‐ Yu; Yu, Chu ‐ Guo; Xu, Zheng ‐ Yang; Yu, Hai ‐ Zhu; Xiao, Bin; Fu, Yao
- Abstract
A novel copper-catalyzed regiodivergent alkylboration of alkenes with bis(pinacolato)diboron and alkyl halides has been developed. The regioselectivity of the alkylboration was controlled by subtle differences in the ligand structure. The reaction thus enables the practical, regiodivergent synthesis of two different alkyl boronic esters with complex structures from a single alkene.
- Subjects
LIGANDS (Chemistry); COPPER catalysts; ALKENES; CHEMICAL reactions; MOLECULAR structure
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 44, p13149
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201506713