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- Title
Synthesis of Allyl Carbamates through the Regioselective Domino Reaction of Amines, CO<sub>2</sub>, and Unsymmetrical Allyl Chlorides under Pd Catalysis.
- Authors
Cai, Juewang; Zhang, Min; Zhao, Xiaoming
- Abstract
The regioselective domino reaction of CO2 (1 atm), amines, and unsymmetrical allyl chlorides in the presence of a palladium complex and K3PO4 under mild conditions to provide allyl carbamates in good yields with excellent regioselectivity (99:1) was accomplished.
- Subjects
CARBAMATES; REGIOSELECTIVITY (Chemistry); ALLYL chloride; PALLADIUM catalysts; ENVIRONMENTAL chemistry
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 27, p5925
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201500769