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- Title
Benzoyl Peroxide Promoted Radical ortho-Alkylation of Nitrogen Heteroaromatics with Simple Alkanes and Alcohols.
- Authors
Fang, Lei; Chen, Liangshun; Yu, Jianjun; Wang, Limin
- Abstract
A catalytic amount of benzoyl peroxide (BPO)-initiated cross-dehydrogenative coupling reaction of N-iminopyridine ylides with simple alkanes and alcohols leads to the corresponding 2-alkylpyridines with high regioselectivity in moderate to good yields without an additional reduction step to remove the activated group.
- Subjects
BENZOYL peroxide; CATALYSIS synthesis; DEHYDROGENATION; COUPLING reactions (Chemistry); BENZOYL compounds; YLIDES; ALKANES; CONFERENCES &; conventions
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 9, p1910
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201403479