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- Title
Roadmap towards N-Heterocyclic [2.2]Paracyclophanes and Their Application in Asymmetric Catalysis.
- Authors
Busch, Mark; Cayir, Merve; Nieger, Martin; Thiel, Werner R.; Bräse, Stefan
- Abstract
A novel family of [2.2]paracyclophane derivatives is described. Different substituted pyrazole, triazole and pyrimidine moieties were introduced to the [2.2]paracyclophane scaffold and the products were characterized spectroscopically and by X-ray structure analysis. These compounds are promising ligands for application in asymmetric catalysis. We show here that one of these ligands can catalyze asymmetric conjugate addition. Furthermore a palladium complex was synthesized by using a hydroxy-pyrazolyl[2.2]paracyclophane ligand.
- Subjects
PARACYCLOPHANES; CYCLOPHANES; CATALYSIS; PHYSICAL &; theoretical chemistry; SURFACE chemistry
- Publication
European Journal of Organic Chemistry, 2013, Vol 2013, Issue 27, p6108
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201300508