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- Title
A Visible-Light-Harvesting Assembly with a Sulfocalixarene Linker between Dyes and a Pt-TiO<sub>2</sub> Photocatalyst.
- Authors
Kamegawa, Takashi; Matsuura, Sachiyo; Seto, Hiroki; Yamashita, Hiromi
- Abstract
Successful anchoring of cationic dye molecules (thiazole orange, TO) on Pt‐TiO2 for a visible‐light‐harvesting assembly was achieved by surface modification of Pt‐TiO2 with 4‐sulfocalix[4]arene as a linker, leading to formation of surface complexes (see picture). This heterogeneous system can act as an efficient photocatalyst for production of hydrogen in the presence of a sacrificial reagent (TEOA=triethanolamine).
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 3, p916
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201206839