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- Title
Hydroarylations of Heterobicyclic Alkenes through Rhodium-Catalyzed Directed CH Functionalizations of S-Aryl Sulfoximines.
- Authors
Dong, Wanrong; Parthasarathy, Kanniyappan; Cheng, Ying; Pan, Fangfang; Bolm, Carsten
- Abstract
Rhodium-catalyzed directed CH-functionalizations have been used in hydroarylations of heterobicyclic alkenes with NH-sulfoximines. Unexpectedly, the bicyclic framework is retained, resulting in the formation of addition products being attractive intermediates for functionalized molecules that are difficult to prepare by other means.
- Subjects
RHODIUM; ALKENE photocycloaddition; SULFOXIMINES; ALKENES; HYDROCARBONS
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 48, p15732
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201404859