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- Title
[Au]/[Pd] Multicatalytic Processes: Direct One-Pot Access to Benzo[ c]chromenes and Benzo[ b]furans.
- Authors
Oonishi, Yoshihiro; Gómez ‐ Suárez, Adrián; Martin, Anthony R.; Makida, Yusuke; Slawin, Alexandra M. Z.; Nolan, Steven P.
- Abstract
A new synthetic protocol that combines the advantages offered by eco-friendly solvent-free reactions and sequential transformations is reported. This strategy offers straightforward access to benzo[ c]chromenes and benzo[ b]furans from commercially available starting materials. This two-step, one-pot strategy consists of an Au-catalyzed hydrophenoxylation process followed by Pd-catalyzed CH activation or Mizoroki-Heck reactions. The selectivity of the process towards CH activation or Mizoroki-Heck reaction can be easily tuned.
- Subjects
SOLVENTS; CHEMICAL reactions; SEQUENTIAL analysis; BENZOATES; HECK reaction
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 42, p13507
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201404630